444 is a molybdenum-alloyed, dual-stabilized (titanium and niobium) ferritic stainless steel containing about 18% chromium and 2% molybdenum, with no deliberate nickel. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.
With nominally 18% chromium and 2% molybdenum and ultra-low carbon and nitrogen, 444 provides corrosion resistance approaching that of type 316 — including pitting and crevice-corrosion resistance — while, as a ferritic grade, being essentially immune to chloride stress-corrosion cracking. The titanium and niobium stabilization ties up carbon and nitrogen, so the steel can be welded in all dimensions without sensitisation or post-weld annealing. Being nickel-free it is magnetic, cannot be hardened by heat treatment, has good cold formability, and offers good high-temperature oxidation resistance to about 1000 °C.
Typical applications include hot-water tanks and solar water heaters, automotive exhaust systems, heat exchangers, brewing and food-processing equipment, electric kettles, and outdoor panels.
Typical values, annealed condition.
| Property | Value | Unit |
|---|---|---|
| Density | 7.7 | g/cm³ |
| Melting range | 1480–1530 | °C |
| Elastic modulus | 220 | GPa |
| Coefficient of thermal expansion (20–100 °C) | 10.4 | µm/m·°C |
| Thermal conductivity (100 °C) | 26.8 | W/m·K |
| Specific heat (20 °C) | 460 | J/kg·K |
| Structure | Ferritic | — |
Specified per ASTM A240 (UNS S44400).
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Iron | Fe | Balance | — | Base element |
| Chromium | Cr | 17.5 | 19.5 | Corrosion / oxidation resistance |
| Molybdenum | Mo | 1.75 | 2.50 | Pitting / crevice corrosion resistance |
| Titanium + Niobium | Ti+Nb | 0.20 + 4×(C+N) | 0.80 | Dual stabiliser; ties up C and N |
| Nickel | Ni | — | 1.00 | Residual |
| Manganese | Mn | — | 1.00 | Deoxidiser |
| Silicon | Si | — | 1.00 | Deoxidiser |
| Carbon | C | — | 0.025 | Ultra-low (weldability) |
| Nitrogen | N | — | 0.035 | Ultra-low (stabilised) |
| Phosphorus | P | — | 0.040 | Residual impurity |
| Sulphur | S | — | 0.030 | Residual impurity |
Nominal: 18Cr-2Mo dual-stabilized (Ti + Nb) ultra-low-carbon ferritic stainless steel.
Annealed condition, per ASTM A240 for UNS S44400.
| Condition | Property | Value |
|---|---|---|
| Annealed | Tensile strength (UTS) | ≥415 MPa |
| Annealed | 0.2% yield strength | ≥275 MPa |
| Annealed | Elongation at break | ≥20 % |
| Annealed | Hardness | ≤217 HB (~96 HRB) |
| — | Elastic modulus | 220 GPa |
Confirm against the mill test report.
| Environment | Performance | Notes |
|---|---|---|
| Atmospheric / general | Excellent | Approaches type 316 |
| Chloride pitting / crevice | Very Good | 2% Mo; similar to 316 |
| Chloride stress-corrosion cracking | Excellent | Ferritic — essentially immune (advantage over 316) |
| Mild acids / potable & hot water | Very Good | Common tank / heater application |
| Oxidation (elevated temperature) | Very Good | Useful to ~1000 °C |
The 2% molybdenum gives pitting and crevice resistance similar to 316, while the ferritic structure provides essentially complete immunity to chloride stress-corrosion cracking — a key advantage over austenitic 304/316.
A ferritic grade; cannot be hardened by heat treatment. Properties are set by annealing.
Anneal Heat to approximately 850–950 °C and air cool. Owing to dual stabilization, post-weld annealing is not required to restore intergranular corrosion resistance. Avoid prolonged exposure near 475 °C (embrittlement).
Excellent weldability without sensitisation owing to titanium/niobium stabilization; can be welded in all dimensions without post-weld annealing. Note low toughness at the ductile-to-brittle transition in heavier sections.
| Welding Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Very Good | AWS A5.9 ER430LNb / stabilized ferritic, or Ni-base |
| GMAW / MIG | Good | Stabilized ferritic filler |
| Resistance / seam | Very Good | — |
Use a stabilized stainless or nickel-base filler to maintain weld-metal corrosion resistance. No post-weld anneal required.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Machinability | Good; similar to other ferritic grades |
| Work hardening | Low rate — does not harden excessively |
| Coolant | Ample flood coolant |
Forming Processes
| Process | Notes |
|---|---|
| Cold forming | Good — roll forming, mild stretch bending, drawing |
| Hot forming | ~1100–800 °C; anneal afterward |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Water heating | Hot-water tanks, solar water heaters, kettles | SCC immunity + corrosion resistance |
| Automotive | Exhaust systems, trim | Corrosion + oxidation resistance |
| Food / brewing | Brewing and processing equipment | Corrosion resistance + hygiene |
| Heat transfer | Heat exchangers, condensers | Chloride resistance + thermal conductivity |
| Product Form | ASTM Standard | ASME Code |
|---|---|---|
| Plate, sheet and strip | ASTM A240 | ASME SA-240 |
| Seamless / welded tube | ASTM A268 | ASME SA-268 |
| Bar and shapes | ASTM A479 | — |
| Welding consumables | AWS A5.9 ER430LNb | — |
Molybdenum-alloyed, dual-stabilized ferritic stainless steel. UNS S44400.
| Grade | Cr % | Mo % | Stabiliser | Best Used For |
|---|---|---|---|---|
| 444 | 17.5–19.5 | 1.75–2.5 | Ti + Nb | 18Cr-2Mo ferritic; 316-like corrosion, SCC immunity |
| 441 | 17.5–18.5 | — | Nb + Ti | 18Cr dual-stabilized; hot exhaust |
| 439 | 17–19 | — | Ti | 18Cr-Ti ferritic; cold-end exhaust |
| 430 | 16–18 | — | — | General ferritic; non-stabilized |
| 316L | 16–18 | 2–3 | — | Austenitic Mo grade (non-magnetic) |




